FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

(A Peer Review Journal)
e–ISSN: 2408–5162; p–ISSN: 2048–5170

FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

OPTIMIZATION OF PROCESSING VISCOSITY OF REACTIVE BLENDING OF DIMETHYOL UREA AND EPOXIDIZED COTTON SEED OIL FOR EMULSION PAINT PRODUCTION
Pages: 523-526
C. S. Archibong, R. Odoh and A. David


keywords: Dimethyol urea, viscosity, epoxidized cotton seed oil, reactive blend

Abstract

The effect of dimethyol urea (DMU) viscosity on a composite obtained from the reactive modification of DMU and epoxidized cotton seed oil ECSO was successfully investigated in this work. Some physico-chemical parameters of the Dimethyol urea obtained at different DMU viscosities (13.75 – 27.80 mpa.s) were evaluated. The Density, formaldehyde emission, melting point, refractive index were seen to increase with increasing DMU viscosity. DMU viscosity below 22.08 mpa.s was seen to produce DMU/ECSO blend soluble in water and beyond this value the composite became insoluble. The processing of DMU/ECSO composite by formulators for the development of an emulsion paint could therefore be suggested below the value.

References

Nawaz M, Rehman W & Baloch MK 2010. Issues of road disposed habit municipal solid waste, environmental impacts and implementation of sound management practices in developing countries "Nigeria”. Int. J. Environs. Sci. and Deve., 1(5): 0210-0264. Newell Rubbbermaid 2014. Open Global E-commerce HUB PAINT MAKING. New York city, United States. Dinda S, Patwardhan AV, Goud VV & Pradhan NC 2008, Epoxidation of cottonseed oil by aqueous hydrogen peroxide catalysed by liquid inorganic acids. Bioresource Technology, 99(9): 3737-3744. Mirmohseni A & Hassanzadeh V 2000. Application of polymer – Coated quartz crystal microbalance (QCM) as a sensor for BTEX compounds vapours. J. Appl. Polym. Sci., 79: 1062-1065. AOAC 2000. Official methods of Analysis Internmational (Horwitz W. Edition) Gaiithershur. USA. 17th Edition, Vol. 1(41): 30-35. Osemeahon SA & Archibong CA 2011. Development of urea formaldehyde and polyethylenewaste as a copolymer binder for emulsion paint formulation. J. Toxicol. Environ, Health Sci., 3(4): 101-108. Kim GM 2001. Examination of selected synthesis parameters for wood adhesive – type urea – formaldehyde resins by CNMR spectroscopy. J. Appl. Polym. Sci., 80: 2800-2814. Petrovic ZS, Zlatanic A, Lava CC & Sinadinovic S 2002. Epoxidation of soya bean oil in toluene with peroxoacetic acid and peroxoformic acids-kinetics and side reactions. Eur. J. Lipid Sci. & Techn., 104(5): 293-299. Pizzi A, Zhao C, Kamoun C, Heinrich H 2002. TTT and CHT curring diagrams of water borne polycondensate resins on lignocellulosic substractes. J. Appl. Polym. Sci., 80: 2128-2139. Velu S, Muruganandam L & Arthanareeswana G 2011. Performance enhancement of polysulfone ultra filtration membrane by blending with polyurethane hydrophilic polymer. Inter. J. of Chem. & Analytical Sci., 2(7): 87-92. Kaniappan K & Latha S 2011: Certain investigations on the formulation and characterization of polystyrene/poly(methyl methacrylate) Blends. Int. J. Chem. Tech. Res., 3(2: 708-717. Devi R & Maidivanne R 2012. Normal coordinate analysis of polyvinyl acetate. Engr. Sci. & Techn.: An International Journal, 2(4): 795-799. Akinterinwa A, Osemeahon SA, Nkafamiya II & Dass PM 2015: Formulation of emulsion paint from a copolymer composite of dimethyol urea/polystyrene. Chemistry and Materials Research, 7(7): 20-25. Vaidya R, Chaudhary G, Raut N, Shinde G & Deshmukh N 2012. Synthesis of biocomposites from natural oils. A Review. International Conference on Environmental, Biomed. and Biotech. Ipcbee 41: 56. Alavi MM, Nikje F Abedinifar and Idris A 2011 Epoxidized soybean oil ring opening reaction under MW Irradiation, 3(3): 383-388. Toloei A, Atashin S & Bahrololoom ME 2013 A new approach in modifying polymeric coatings to increase corrosion resistance properties. ISRN material science 2013, 1-7. Cakic MS, Ivana SR, Vladislav MJ, Radmilaz R, Olivera ZI & Jao KB 2012. Investigation of the curing kinetics of alkyd-melamine-epoxy resin system. Progress in Organic Coatings, 73(4): 415-424. Cakir M, Kartal I, Demirer H & Samur R 2012. Effect of water absorption on the wear behavior of sol-gel processed epoxy/silica hybrids. Scientific Research and Essays, 7(7): 805-812. Shagal MH, Barminas JT, Aliyu BA & Osemeahon SA 2013. Epoxidation of Ximenia Americana seed oil. J. Petroleum Techn. and Alternative Fuels, 4(4): 72-77. Myint S, Zakaria MSB & Ahmed KR 2010. Paint Based on Waste Expanded Polystyrene Progress in Rubber, Plastic and Recycling Technology. Opara CC, Sokore B & Ugwo PN 2013. production and study of factors affecting the flexibility of polyester paint using local materials. Int. J. Eng. and Sci. Research, 3: 2583-2588. Paula, Y. (2011). Organic chemistry, 6th edition, pearson education. Inc. Publishing as Prentice Hall, pp. 1178- 1180. Bhattacharya A, James W & Rawlins PR 2009. Poly grafting and crosslinking. Published by John Wiley & Sons, Inc., Hoboken, New Jersey, pp. 276-281. Blessed DJ 2012. Development of Urea Formaldehyde and Polystyrene Waste as Copolymer Binder for Emulsion Paint. Dale MB 2004. A novel synthesis of palm oil and palm kernel oil- derived polyamide resins as surface coatings for leather. Nigerian J. Polymer Sci. Techn., 4: 295 – 304. Ruhlman D 2010. Reflection on water: New dispersant and rheology modifiers for gloss emulsion system (waterborne alkyds). European Coating Journal, pp. 18. Saurabh Tayde, Patnaik M Bhagt SL & Renge VC 2011. Epoxidation of vegetable oils: Shashi C 2011. A textbook of engineering chemistry. Dhanpat Rai & CO (PVT) Ltd., pp. 71-72. Shinde Nilesh, Mukesh Kathalewar & Anagha Sabnis 2012. Synthesis and characterization of emulsion polymers using isopropenyl acetate. Stephanie P 2011. Oldest human paint making studio discovered in cave. Live Science Retrieved Oct. 14, 2011.

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